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It may be Donald Trump's time in the spotlight, but it was his wife Melania and daughter Ivanka who took center stage with their stunning attire at the national prayer service on Saturday morning.

The new first lady, who wore a baby blue Ralph Lauren ensemble for the inauguration on Friday, was dressed to the nines in a chic A-line black belted coat and cobalt patent Louboutin pumps at the Washington National Cathedral.

Ivanka Trump arrived with her husband and family, donning a striking Oscar de la Renta velvet wrap dress with a matching handbag, headband, and leather gloves.

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It may be Donald Trump's moment in the spotlight, but it was Melania and Ivanka who stood out in their stunning ensembles

Arriving in style: First Lady Melania arrives at the cathedral in a chic black, A-line coat at the national prayer service with President Trump in a chic black coat

Chic in black: Melania's outfit is a solemn contrast to her baby blue Ralph Lauren ensemble she sported on Inauguration Day

Looking presidential: Donald Trump sported a black suit as he and the First Lady walks by his side in her cobalt patent Louboutin pumps

Everyone wants a picture: A member of the cathedral's clergy was among those taking photographs of the First Couple as they arrived for the service

Red velvet: The First Daughter donned a stunning plush velvet wrap dress with a matching handbag, gloves, and headband

Ivanka dressed in an Oscar de la Renta ensemble, complete with an Aspinal of London handbag, walks alongside daughter Arabella, as she arrives at the interfaith prayer service at the Washington cathedral

Ivanka and husband Jared Kushner arrive with children Arabella dressed in white, Joseph, right, and Baby Theo

All hands: Jared Kushner, Ivanka Trump's husband and senior adviser to the president, held the couple's younger son Theodore in his arms and Joseph by the hand

The family takes a seat at Washington National Cathedral before the prayer begins

The first and second families arrived at the interfaith service at 10.30am - an inauguration tradition that dates back to George Washington's presidency

Don Jr., his wife in a maroon coat, Jared Kushner and wife Ivanka, clad in a cranberry coat, entered first, taking their seats in the second row, the Kushners on the right and the Trumps on the left.

Tiffany Trump was seated in the third row on the left, as well, wearing a white coat.

The Pences came in next, Karen Pence in a black outfit with a large, light pink collar, and the Vice President in a black suit and maroon striped tie, taking their seats in the front row.

President Trump also wore a black suit to the prayer service. His tie was dark blue with small white stripes. Melania wore her brunette hair down, after an up-do at Friday's inauguration.

Family time: Vanessa Trump, the president's daughter-in-law, led his eldest granddaughter Kai at the front of the First Family as they arrived. Her husband, Donald Trump Jr was directly behind, followed by the president's younger daughter Tiffany, with her boyfriend Ross Mechanic, and behind them Lara Trump, and her husband Eric, the president's second son

Arrivals: Vice-president Mike Pence and his wife Karen arrived shortly before the President and the First Lady for the service

Don Jr., and his wife in a maroon coat, take seats in the row behind the President, First Lady, Vice President Mike Pence, and wife Karen Pence

The first and second family stand during the national prayer service, Tiffany Trump was seated in the third row on the left, wearing a white coat

Praying for the presidency: Donald Trump and Melania Trump are in the front row at Washington National Cathedral as an interfaith service of prayer rounds off his inauguration