About 60 percent of the Energy Department’s budget is devoted to the National Nuclear Security Administration, which defines its mission as enhancing national security through the military application of nuclear science. Under President Obama, the Energy Department helped secure an agreement with Iran to dismantle its nuclear weapons program and took on a larger role in efforts to combat global warming, particularly through scientific research. It also established the Advanced Research Projects Agency-Energy to support breakthrough research on clean energy technology.

The last two energy secretaries, Ernest J. Moniz of M.I.T. and Steven Chu of Stanford, brought to the office their doctorates in physics, academic credentials and, in Dr. Chu’s case, a Nobel Prize.

Mr. Perry, 66, would bring a different set of credentials. He is the longest-serving governor of Texas — in office from 2000 to 2015 — and before that was the Texas agriculture commissioner. He holds a bachelor’s degree in animal science from Texas A&M University.

In his 2010 book, “Fed Up! Our Fight to Save America From Washington,” Mr. Perry called the established science of human-caused climate change a “contrived, phony mess.” His views align with those of Mr. Trump, who has called climate change a hoax perpetuated by the Chinese.

More recently, Mr. Perry was a contestant on the television show “Dancing With the Stars,” but was eliminated in an early round.

He was briefly a front-runner for the 2012 Republican presidential nomination, but his Energy Department “oops moment,” as he called it, is widely seen as having sunk his candidacy. His run for the 2016 nomination ended in late 2015, but not before he called Mr. Trump a “barking carnival act” and a “cancer on conservatism.”

Mr. Perry did campaign energetically for Mr. Trump later.

Mr. Trump’s selection of Mr. Perry appears to line up with his appointment last week of the Oklahoma attorney general, Scott Pruitt, to run the Environmental Protection Agency. Mr. Pruitt — who, like Mr. Perry, is skeptical of climate change — has built a career out of suing the agency he is now set to lead and seeking to dismantle its rules and authority.